Host–guest complexes with tuneable solid state structures

Fully tuneable, Purcell-enhanced solid-state quantum emitters

Manganese(II) chloride complexes with pyridine N-oxide (PNO) derivatives and their solid-state structures

Three manganese(II) N-oxide complexes have been synthesized from the reaction of manganese(II) chloride with either pyridine N-oxide (PNO), 2-methyl-pyridine N-oxide (2MePNO) or 3-methyl-pyridine N-oxide (3MePNO). The compounds were synthesized from methano-lic solutions of MnCl2·4H2O and the respective N-oxide, and subsequently characterized structurally by single-crystal X-ray diffraction. Th...

Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes: Synthesis, Solid-State Structures, and Quantum Chemistry Calculations

The reaction of (η(5)-C(5)H(5))Co(PPh(3))(2) with 1,3-bis(isopropyl)imidazol-2-ylidene (Im(i)Pr(2)) leads to the formation of (η(5)-C(5)H(5))Co(PPh(3))(Im(i)Pr(2)). In a similar fashion (η(5)-C(5)H(5))Co(Im(i)Pr(2))(CO) is formed from (η(5)-C(5)H(5))Co(CO)(2). The barrier to rotation about the Co-C(carbene) bond in the latter complex has been determined by variable-temperature (1)H NMR spectros...

Alkali Metal Picrate Complexes of “Crowned”-Phthalocyanines. Solid State Structures and Electrical Properties

Se Solid - state NMR Spectroscopy and Structures of Tetramethylammonium Pentaselenide and Hexaselenide Complexes

High-resolution 77Se solid-state NMR spectra are reported for [NMe4]2Ses and [NMe4]2Se6. The isotropic chemical shifts for the former are similar to those observed for the Ses2ion in solution, suggesting that the conformation adopted by the anion is similar in the solid state and solution. The agreement between the chemical shifts for the Ses2anion in the solid state and solution is less good. ...